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A diesel particulate filter (top left) in a Peugeot
A diesel particulate filter, sometimes called a DPF, is a device designed to remove diesel particulate matter or soot from the exhaust gas of
a diesel engine. Wall-flow diesel particulate filters usually remove
85% or more of the soot, and can at times (heavily loaded condition) attain soot removal efficiencies of
close to 100%. A diesel-powered vehicle equipped with
functioning filter will emit no visible smoke from its exhaust pipe.
In addition to collecting the particulate, a method must
exist to clean the filter. Some filters are single-use (disposable), while others are designed to burn off the
accumulated particulate, either through the use of a catalyst (passive), or through an active technology, such
as a fuel burner which heats the filter to soot combustion temperatures, through engine modifications (the
engine is set to run a certain specific way when the filter load reaches a pre-determined level, either to heat
the exhaust gases, or to produce high amounts of NO2, which will oxidize the
particulates at relatively low temperatures), or through other methods. This is known as "filter
regeneration". Sulfur in the fuel
interferes with many "regeneration" strategies, so almost all jurisdictions that are interested in the
reduction of particulate emissions, are also passing regulations governing fuel sulfur levels.
History
Particulate filters have been in use on non-road
machines since 1980, and in automobiles since 1996. Diesel engines during combustion of the fuel/air mix
produce a variety of particles generically classified as diesel particulate matter due to incomplete
combustion. The composition of the particles varies widely dependent upon engine type, age, and the emissions
specification that the engine was designed to meet. Two-stroke diesel
engines produce more particulate per unit of power than do four-stroke diesel
engines, as they burn the fuel-air mix less completely.
Historically diesel engine emissions were not regulated
until 1987 when the first California Heavy Truck rule was introduced capping particulate emissions at 0.60
g/BHP Hour. Since then progressively tighter standards have been introduced for both On-Road and Non-Road diesel engines.
While particulate emissions from diesel engines were
first regulated in the United States, similar regulations have also been adopted by
the European Union, most Asian countries, and the rest
of North and South America World List of Standards.
While no jurisdiction has made filters mandatory, the
increasingly stringent emissions regulations that engine manufactures must meet mean that eventually all
on-road diesel engines will be fitted with them. The American 2007 heavy truck engine emissions regulations
cannot be met without filters. In the European Union, filters are expected to be necessary to meet Euro.VI
heavy truck engine emissions regulations currently under discussion and planned for the 2012-2013 time
frame. PSA Peugeot Citroën was the first company to make them standard fit on passenger cars in
2000, in anticipation of the future Euro V regulations.
It is expected that non-road diesel engines will be
regulated in a similar manner.
As of December 2008 the California Air Resources Board
(CARB) has established diesel emissions regulations
which—with variance according to vehicle type, size and usage—require that in-use diesel engines (in
California) be retrofitted, repowered or replaced in order to remove at least 85% of particulate matter
(PM) emitted from diesel engines. Retrofitting the engines with CARB verified diesel particulate filters
are one way to fulfil this requirement.[1] In 2009 the American
Recovery and Reinvestment Act provided funding to assist
owners in offsetting the cost of diesel retrofits for their vehicles.[2]
Other jurisdictions may also do this. A variety of
retrofit programs have been done:
Variants of DPFs
Cordierite Diesel Particulate Filter on GM 7.8 Isuzu
Unlike a catalytic converter which is a flow-through device, a DPF cleans exhaust gas by forcing the
gas to flow through the filter. There are a variety of diesel particulate filter technologies on the market.
Each is designed around similar requirements:
- Fine filtration
- Minimum pressure drop
- Low cost
- Mass production suitability
- Product durability
Cordierite wall flow filters
The most common filter is made of cordierite (a ceramic
material that is also used as catalytic converter supports (cores)). Cordierite filters provide excellent
filtration efficiency, are (relatively) inexpensive, and have thermal properties that make packaging them
for installation in the vehicle simple. The major drawback is that cordierite has a relatively
low melting point (about 1200 °C) and cordierite substrates have been known to melt down during
filter regeneration. This is mostly an issue if the filter has become loaded more heavily than usual, and is
more of an issue with passive systems than with active systems, unless there is a system break down.
Cordierite filter cores look like catalytic converter
cores that have had alternate channels plugged - the plugs force the exhaust gas flow through the wall and the
particulate collects on the inlet face.
Silicon carbide wall flow filters
The second most popular filter material
is silicon carbide, or SiC. It has a higher (2700 °C) melting point than cordierite, however it
is not as stable thermally, making packaging an issue. Small SiC cores are made of single pieces, while
larger cores are made in segments, which are separated by a special cement so that heat expansion of the
core will be taken up by the cement, and not the package. SiC cores are usually more expensive than
cordierite cores, however they are manufactured in similar sizes, and one can often be used to replace the
other.
Silicon carbide filter cores also look like catalytic
converter cores that have had alternate channels plugged - again the plugs force the exhaust gas flow through
the wall and the particulate collects on the inlet face.
Ceramic Fiber Filters
Fibrous ceramic filters are made from several different
types of ceramic fibers that are mixed together to form a porous media. This media can be formed into almost
any shape and can be customized to suit various applications. The porosity can be controlled in order to
produce high flow, lower efficiency or high efficiency lower volume filtration. Fibrous filters have an
advantage over wall flow design of producing lower back pressure.
Metal fiber flow through filters
Some cores are made from metal fibers - generally the
fibers are "woven" into a monolith. Such cores have the advantage that an electrical current can be passed
through the monolith to heat the core for regeneration purposes, allowing the filter to regenerate at low
exhaust temperatures and/or low exhaust flow rates. Metal fiber cores tend to be more expensive than cordierite
or silicon carbide cores, and generally not interchangeable with them.
Paper
Disposable paper cores are used in certain specialty
applications, without a regeneration strategy. Coal mines are common
users — the exhaust gas is usually first passed through a water trap to cool it, and then through the
filter. Paper filters are also used when a diesel machine must be used indoors for short periods of time,
such as on a forklift being used to install equipment inside of a store.
Partial filters
There are a variety of devices that produce over 50%
particulate matter filtration, but less than 85%. Partial filters come in a variety of materials. The only
commonality between them is that they produce more back pressure than a catalytic converter, and less than a
diesel particulate filter. Partial filter technology is popular for retrofit.
Filter usage
A properly designed filter will have little effect on
fuel usage. However, improper installation can be catastrophic, which is why automobile and truck engine
manufacturers have avoided the use of filter technology until now. It was first offered as standard by the
French manufacturer PSA Peugeot Citroën in early 2000, and has been a huge success.[citation needed] Slow adoption by the German car industry
sparked local protests in March 2005.[citation needed]
Maintenance
Filters require more maintenance than catalytic
converters. Engine oil ash builds up on the surface of the inlet face of the filter, and will eventually clog
the pores. This increases the pressure drop over the filter, which when it reaches 3.6 pounds per square
inch (25 kPa) or higher it is capable of causing engine damage. Regular filter maintenance is a
necessity.[3]
Regeneration
Metering pump for Diesel or additive injection, 3 L/h at 5 bar
Regeneration is the process of removing the accumulated
soot from the filter. This is done either passively (by adding a catalyst to the filter) or actively. On-board
active filter management can use a variety of strategies:
- Engine management to increase exhaust temperature
- Use of a fuel borne catalyst to reduce soot burn-out temperature
- A fuel burner to increase the exhaust temperature
- A catalytic oxidizer to increase the exhaust temperature, with after
injection (HC-Doser)
- Resistive heating coils to increase the exhaust temperature
- Microwave energy to increase the particulate temperature
All on-board active systems use extra fuel, whether
through burning to heat the DPF, or providing extra power to the DPF's electrical system, although the use of a
fuel borne catalyst reduces the energy required very significantly. Typically a computer monitors one or more
sensors that measure back pressure and/or temperature, and based on pre-programmed set points the computer
makes decisions on when to activate the regeneration cycle. The additional fuel can be supplied by
a metering pump. Running the cycle too often while keeping the back
pressure in the exhaust system low will use extra fuel. Not running the regeneration cycle soon enough
increases the risk of engine damage and/or uncontrolled regeneration (from an excess of accumulated soot)
and possible DPF failure. Quality regeneration software is a necessity for longevity of the active DPF
system.
Diesel particulate matter combusts when temperatures
above 600 degrees Celsius are attained. This temperature can be reduced to somewhere in the range of 350 to 450
degrees Celsius by use of a fuel borne catalyst. The actual temperature of soot burn-out will depend on the
chemistry employed. The start of combustion causes a further increase in temperature. In some cases, in the
absence of a fuel borne catalyst, the combustion of the particulate matter can raise temperatures above the
structural integrity threshold of the filter material, which can cause catastrophic failure of the substrate.
Various strategies have been developed to limit this possibility. Note that unlike a spark-ignited engine,
which typically has less than 0.5% oxygen in the exhaust gas stream before the emission control device(s), many
diesel engines run above 15% oxygen pre-filter. While the amount of available oxygen makes fast regeneration of
a filter possible, it also contributes to runaway regeneration problems.
Some applications use off-board regeneration. Off-board
regeneration requires operator intervention (i.e. the machine is either plugged into a wall/floor mounted
regeneration station, or the filter is removed from the machine and placed in the regeneration station).
Off-board regeneration is not usable for on-road vehicles, except in situations where the vehicles are parked
in a central depot when not in use. Off-board regeneration is mainly used in industrial and mining
applications. Coal mines (with the attendant explosion risk from coal damp) use off-board regeneration if
non-disposable filters are installed, with the regeneration stations sited in an area where non-permissible
machinery is allowed.
Many forklifts may also use
off-board regeneration - typically mining machinery and other machinery that spend their operational lives
in one location, which makes having a stationary regeneration station practical. In situations where the
filter is physically removed from the machine for regeneration there is also the advantage of being able to
inspect the filter core on a daily basis (DPF cores for non-road applications are typically sized to be
usable for one shift - so regeneration is a daily occurrence).[4]
Diesel Oxidation Catalyst (DOC)
DOCs is the other diesel retrofit system. They
are devices that use a chemical process to break down pollutants in the exhaust stream into
less harmful components. More specifically, DOCs utilise palladium and platinum catalysts to
reduce the particulate matter (PM), hydrocarbon based soluble organic fraction (SOF), and carbon monoxide
content of diesel exhaust by simple oxidation:
CO + ½O2 → CO2
[HC] + O2 → CO2 + H2O
Retrofit solutions and certification
When used in a retrofit application to reduce the
emissions of an older vehicle, the devices may require certification and approval. Schemes such as
the London low emission zone require equipment to be certified for use on a particular vehicle or
engine, together with an annual inspection of vehicles to ensure they are still operating as expected.
- ^ http://www.econixusa.com/diesel-emissions-regulations.html
- ^ http://www.recovery.gov/About/Pages/About.aspx
- ^ - DPFRegeneration.com - Clean and Thermal Bake Diesel Particulate Filters
- ^ Bruce R. Conrad, "Diesel Emissions Evaluation Program - INCO" Diesel Emissions
Evaluation Program Website (May 2006)